壳聚糖在荔枝果酒澄清中的应用研究

研究了壳聚糖对荔枝果酒的澄清作用,比较了荔枝果酒用壳聚糖处理前后的主要成分的变化.结果表明,经壳聚糖处理后可溶性固形物、酚类物质、可溶性蛋白质、果胶、酒精度、色度等均有不同程度的下降,透光率提高.当壳聚糖用量为0.6 g.L-1时对荔枝果酒的澄清效果最好,且具有很好的生物稳定性,说明壳聚糖是一种有效的荔枝果酒澄清剂.     

Anatomical variations in wood among four native species of Leguminosae grown in arid areas of China

Morphological features and anatomical variations are described and illustrated in detail for four native species of Legumi-nosae grown in arid sandy regions in China, which are Hedysarum scoparium Fisch.et Mey., Caragana korshiskii Kom., Lespedeza bicolor Turcz. and Ammopiptanthus mongolicus (Maxim. ex Kom.) Cheng f. All species showed similar morphological features: distinct growth ring boundaries, ring to semi-ring-porosity, simple perforation plates, alternate intervessel pitting, nonseptate fibers, para...     

速生杨硫酸盐浆中木素的存在对纤维素水解反应性能及其产物结构的影响(英文)

对木素含量为0.9％～8.3％的速生杨硫酸盐浆进行了X-射线分析研究。利用多相水解方法测定了其反应性能。研究确定,浆中结晶纤维素含量取决于木素脱出程度并随着木素含量的降低而增加。木屑和浆中的纤维素结晶度相当高,而在脱木素过程中只呈微小变化。木素存在于多相水解反应过程中起着阻碍纤维素水解的作用,降低其反应速度常数。基于研究结果还提出了木素与纤维素结晶部分外表面联结的结论,并探讨了这种联结键的可能方式.     

国外纸业用竹近况

本文综述国外对竹子特性及其在制浆造纸工业利用的近况。包括竹子的备料、制浆、漂白和废液处理等,其中较为详细地叙述了竹子的硫酸盐法,碱性亚硫酸盐—蒽醌法制浆和硫酸盐浆的漂白研究。对于某些工厂应用的实例也有介绍。     

小型枝桠削片机的结构分析

小型枝桠削片机主要用于伐区加工直径为60～80 mm的枝桠,要求其体积小、结构简单、移动方便和易于操纵,因此在结构设计上有其特殊性.在分析其结构特点的基础上,找出影响木片加工质量的因素,提出改进建议,以利于产品的设计和改进.     

Sorption of Cr(VI) on the wood of Japanese larch treated with concentrated sulfuric acid

A carbonaceous sorbent was prepared from the wood of Japanese larch (Larix leptolepis) by dehydration with concentrated sulfuric acid in a 69% yield. The abilities of the sorbent to remove Cr(VI) from aqueous solutions were investigated. Research parameters included the initial solution pH, temperature, and initial concentration of Cr(VI) in solution. The removal of Cr(VI) was highly solution pH dependent and was mainly governed by physicochemical sorption under weak acidic conditions. The equilibrium data fit well in the Langmuir isotherm model. The Langmuir constants were calculated at different temperatures, and the sorption capacity increased with rising temperature, indicating the endothermic nature of the Cr(VI) sorption onto the sorbent. The desorption experiments suggest that the Cr(VI) sorption is generally irreversible, owing to strong interaction of HCrO ₄ ⁻ with the active sites of the sorbent.     

木材断口分形的初步研究

木材是一种天然的多孔性生物高分子材料,结构复杂且变异性大,所以木材断裂表面定量分析的难度很高,对于木材内部裂纹产生、发展的研究一直没有大的突破.在木材断裂力学的研究中,国内外科学家运用传统的断裂试验方法研究居多,但普遍结论是规律不明显或找不到规律(费本华,1999).木材研究者们一直在寻找一种定量描述木材断裂表面形态的新指标,并希望在此基础上预测木材强度和了解木材断裂机制(Schmitt et al.,1996;Qin et al.,1999).     

CCA木材防腐剂活性成分检测方法比较试验

文章介绍了CCA木材防腐药剂中CuO、CrO3、As2O5等活性成分的常规化学分析方法,并与仪器分析方法进行了比较。结果表明,常规化学分析与仪器分析的结果相接近,两者之间的偏差很小,不需做修正便可应用于工业生产上。     

酸催化下苯酚液化木材的制备与表征

在硫酸作用下用苯酚对人工林杨木和杉木进行液化,考察反应时间、反应温度等对液化反应的影响,并对液化产物进行表征分析.结果表明:1)在硫酸催化下,杨木和杉木被苯酚液化的历程相似,但残渣含量稍有不同.酸性催化剂不仅对纤维素和半纤维素起作用,对木质素也起作用.2)反应温度比反应时间对液化效率的影响大,二者均能影响液化产物的分子量和分子量分布.通常杉木液化产物的重均分子量高于杨木.3)液化过程中,木质素和半纤维素首先被液化,最后是纤维素.木材组分的分解、酚化和再缩聚反应主宰整个液化动力学过程及液化产物的结构特征.     

Dielectric properties of copper-ethanolamine treated Chinese fir (Cunninghamia lanceolata Hook.)

In order to clarify the interaction between copper and wood substances in wood treated with copper containing water-borne wood preservatives, the dielectric constant ε′ and dielectric loss factor ε″ of untreated wood and wood treated with four concentration levels of copper-ethanolamine (Cu-EA) solutions were determined within a temperature range from –100 to 40°C and a frequency range from 100 to 1 MHz. Three dielectric relaxation processes were observed in the ε″ spectrum; among them R-I is based on the reorientation of methylol groups in the amorphous region of wood cell walls and R-II is related to wood extractives. R-III appeared in Cu-EA treated wood, and its magnitude decreases with the concentration of Cu-EA solutions used in this experiment. This relaxation process was considered to be based on the reorientation of copper-ethanolamine-wood complexes in wood cell walls. At low copper retention, the hydrogen in the complex can form hydrogen bonding with adjacent hydroxyl groups, which results in a strong bonding state between copper and wood; at high copper retention, the numerous copper-ethanolamine complexes not only hinder them from forming hydrogen bonding with adjacent wood molecules due to steric hindrance, but also weaken the interaction between wood molecules themselves, which corresponds to reducing ε″ values of both R-I and R-III processes. The results explain the fact of in-creasing copper leaching in wood treated with high concentration copper-based water-borne preservatives.